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«Guest Medical SAFETY DATA SHEET 3.4g Detergent Sanitiser Tablets SECTION 1: Identification of the substance/mixture and of the company/undertaking ...»

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Revision date: 18.02.2015 Revision: 4 Supersedes date: 16.02.2015

Guest Medical

SAFETY DATA SHEET

3.4g Detergent Sanitiser Tablets

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name ‘PROPULSE’ CHLOR-CLEAN TABLET H8950/MIR

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Disinfection and cleaning, when correctly diluted with water.

1.3. Details of the supplier of the safety data sheet Supplier Guest Medical Limited Unit A6, Larkfield Trading Estate, New Hythe Lane, Aylesford, Kent, ME20 6SW, United Kingdom.

T: +44(0) 1622 791895, (Hours 09:00- 17:00 Mon to Fri) F: +44(0) 1622 716309 enquiries@guest-medical.co.uk Emergency telephone number SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Acute Tox. 4 - H332 Eye Irrit. 2 - H319 STOT SE 3 - H335 Environmental hazards (67/548/ Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification EEC or 1999/45/EC) Xn;R22. Xi;R36/37. N;R50/53.

2.2. Label elements Pictogram Signal word Warning Hazard statements H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H410 Very toxic to aquatic life with long lasting effects.

Page 1 of 8 Revision date: 18.02.2015 Revision: 4 Supersedes date: 16.02.2015 Precautionary statements P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P312 Call a POISON CENTER/doctor if you feel unwell.

P337+P313 If eye irritation persists: Get medical advice/attention.

P391 Collect spillage.

P402+P404 Store in a dry place. Store in a closed container.

P501 Dispose of contents/container in accordance with local regulations.

P305+P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

–  –  –

SECTION 4: First aid measures

4.1 Description of first aid measures Inhalation Move affected person to fresh air at once. Get medical attention. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen.

Ingestion Do not induce vomiting. Remove affected person from source of contamination. Give plenty of water to drink. Get medical attention immediately. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing.

Skin contact Due to the small packaging the risk of skin contact is minimal. In the event of irritation: Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing.

4.2 Most important symptoms and effects, both acute and delayed

4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures

5.1. Extinguishing media Suitable extinguishing media The product is not flammable. Extinguish with the following media: Water spray, dry powder or carbon dioxide.

5.2. Special hazards arising from the substance or mixture Specific hazards Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. Thermal decomposition or combustion products may include the following oxides of the following substances: Carbon, Nitrogen, very corrosive gases or vapours, Chlorine. Hydrogen chloride (HCl), Toxic gases or vapours: Decomposes above 250oC with release of chlorine and other toxic fumes.

5.3. Advice for firefighters Protective actions during firefighting Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Contain and collect extinguishing water.

Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Ensure suitable respiratory protection is worn during removal of spillages in confined areas.

6.2. Environmental precautions Environmental precautions Not considered to be a significant hazard due to the small quantities used. Collect and dispose of spillage as indicated in Section 13.

6.3. Methods and material for containment and cleaning up Methods for cleaning up Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Avoid generation and spreading of dust. Flush

–  –  –





SECTION 7: Handling and storage

7.1. Precautions for safe handling Usage precautions Avoid spilling. Avoid contact with skin and eyes. Do not handle broken packages without protective equipment. Keep away from heat, sparks and open flame. Do not eat, drink or smoke when using the product. Good personal hygiene procedures should be implemented. Avoid inhalation of vapours/spray and contact with skin and eyes. Provide adequate ventilation. Container must be kept tightly closed when not in use. Protect against direct sunlight. Follow instructions and ensure correct dilution of this product before use.

7.2. Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container, in a dry, cool and well-ventilated place. Keep only in the original container.

7.3. Specific end use(s) SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

8.2. Control parameters Occupational exposure limits Short-tern exposure limit (15-minute): WEL, (as Chlorine) 0.5 ppm 1.5mg/m3 fume Long-tern exposure limit (8-hour TWA): WEL, 10 mg/m3 inhalable dust Long-tern exposure limit (8-hour TWA): WEL, 4.0 mg/m3 respirable dust WEL = Workplace Exposure Limits

–  –  –

8.3. Exposure controls Protective equipment Appropriate engineering controls No specific ventilation requirements. This product must not be handled in a confined space without adequate ventilation.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles or face shield.

Page 4 of 8 Revision date: 18.02.2015 Revision: 4 Supersedes date: 16.02.2015 Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible.

Other skin and body protection Avoid contact with the skin. Wear suitable coveralls to avoid exposure to the skin.

Hygiene measures Warn cleaning personnel of any hazardous properties of the product. Do not eat, drink or smoke when using this product. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Provide eyewash station. Persons susceptible to allergic reactions should not handle this product. Good personal hygiene procedures should be implemented.

Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airborne contamination occurs.

Environmental exposure controls Do not allow undiluted product to enter drains.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

–  –  –

Oxidising properties - Does not meet the criteria for classification as oxidising.

9.2. Other information - Not determined SECTION 10: Stability and reactivity

10.1. Reactivity See section 10.3 (possibility of hazardous reactions) for further information.

10.2. Chemical stability Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions Will not polymerise. The following materials may react with the product: Acids, Alkalis, Organic nitro compounds, Amines, Oxidising agents, Reducing agents, Moisture, Peroxides. Contact with acids liberates toxic gas. Under normal conditions of storage and use, no hazardous reactions will occur.

10.4. Conditions to avoid Avoid the following conditions: Water, moisture, heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight.

10.5. Incompatible materials

Materials to avoid Flammable/combustible materials. Organic materials, oils, grease, sawdust, reducing agents, nitrogen-containing compounds, (NaDCC may generate nitrogen trichloride which is explosive).oxidizing substances, acids and alkalis, damp or slightly wet conditions.

10.6. Hazardous decomposition products Heating may generate the following products: Carbon monoxide (CO), Oxides of Nitrogen, Hydrogen chloride (HCl), Isocyanates, Chlorine.

–  –  –

SECTION 11: Toxicological information 11.1.

11.1 Information on toxicological effects Acute toxicity - oral ATE oral (mg/kg) 5,067.04304869 Acute toxicity - dermal ATE dermal (mg/kg) 28409.09090909 Acute toxicity – inhalation ATE inhalation (dusts/mists mg/l) 3.08641975 Inhalation May cause respiratory system irritation.

Ingestion May be harmful if swallowed.

Skin contact Skin irritation should not occur when used as recommended.

Eye contact Irritating to eyes.

Route of entry Inhalation Ingestion. Skin and/or eye contact SECTION 12: Ecological Information Ecotoxicity This product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment.

–  –  –

12.2. Persistence and degradability Persistence and degradability The product is expected to be biodegradable.

12.3. Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil Mobility This product is soluble in water

12.5. Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB

12.6. Other adverse effects Not determined

–  –  –

SECTION 13: Disposal considerations

13.1. Waste treatment methods General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

SECTION 14: Transport information

–  –  –

14.6 Special precautions for user

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations DETERGENT REGULATIONS: CHLOR-CLEAN Tablets contain amongst other ingredients: Less than 5%: Anionic surfactant, phosphate; 15% or over but less than 30%: Chlorine based bleaching agents; Ingredient datasheet as stipulated in Annex VII C Regulation(EC) No 648/2004 on detergent is available from the contact given in section 1 to any medical personnel upon request EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40. CHIP for everyone HSG228. Approved Classification and Labelling Guide (Sixth edition) L131.



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