«Cryl-A-Clean SAFETY DATA SHEET 1. IDENTIFICATION Product Identifier: Cryl-A-Clean Recommended use: Floor Surfacing Dur-A-Flex, Inc. Manufacturer ...»
SAFETY DATA SHEET
Product Identifier: Cryl-A-Clean
Recommended use: Floor Surfacing
95 Goodwin Street
East Hartford, CT 06108
Emergency phone number: 1-800- 424-9300 (CHEMTREC)
Date of Preparation: July 17, 2014
2. HAZARD(S) IDENTIFICATION
Physical Health Flammable Liquid Category 2 Skin Irritation Category 2 Skin Sensitization Category 1 Specific Target Organ Toxicity Single Exposure Category 3 (Respiratory Irritation)
Hazard statement(s) Precautionary statement(s) Highly flammable liquid and vapor. Keep away from heat, sparks, open flames, and hot surfaces.
Causes skin irritation No smoking.
May cause an allergic skin reaction Keep container tightly closed.
May cause respiratory irritation. Ground and bond container and receiving equipment Use explosion-proof electrical, ventilating and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing mist, vapors or spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Page 1 of 6 Cryl-A-Clean 7/17/14 Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves, eye protection and face protection.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical attention.
Wash contaminated clothing before reuse.
The specific identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST-AID MEASURES Inhalation: Remove victim to fresh air. If breathing is difficult, have qualified personnel administer oxygen. If breathing has stopped, administer artificial respiration. Get medical attention.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation or other symptoms develop, get medical attention. Launder clothing before re-use.
Eye contact: Flush with large quantities of water for several minutes, holding the eyelids apart. Get medical attention if irritation persists.
Ingestion: If conscious, rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious or convulsing person. Get medical attention.
Most important symptoms/effects, acute and delayed: May cause respiratory tract, eye and skin irritation.
Prolonged or repeated contact may cause allergic skin reaction (skin rash).
Indication of immediate medical attention and special treatment, if necessary: If skin irritation or sensitization occurs, discontinue use and get medical attention.
5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Use water spray, carbon dioxide or dry chemical. Cool fire exposed containers with water.
Specific hazards arising from the chemical: Vapors are heavier than air and may travel to ignition source and flash back. Heat of fire may cause an exothermic auto polymerization reaction. Emits toxic fumes under fire conditions. Closed containers may explode due to pressure build up when exposed to extreme heat.
Special protective equipment and precautions for fire-fighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing.
6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment, and emergency procedures: Provide explosion-proof ventilation. Avoid contact with skin, eyes or clothing. Avoid breathing vapors. Wear appropriate protective clothing as described in Section 8. Eliminate all ignition sources.
Environmental precautions: Avoid release to the environment. Report releases as required by local, state and federal authorities.
Methods and materials for containment and cleaning up: Contain and collect with an inert absorbent. Place into an appropriate container for disposal.
7. HANDLING AND STORAGEPrecautions for safe handling: Avoid contact with eyes, skin, and clothing. Avoid breathing vapors or mist.
Wash thoroughly after handling. Wear protective clothing and equipment as described in Section 8. Use with adequate ventilation. Ground container when pouring. Keep away from heat, sparks, flames and all sources of ignition. Do not expose to direct sunlight. Empty containers retain product residues and can be hazardous.
Follow all SDS precautions when handling empty containers.
Conditions for safe storage, including any incompatibilities: Store in a cool, dry, well ventilated area. Keep container tightly closed when not in use. Do not store in direct sunlight. Prevent moisture contact. Protect from physical damage. Keep away from oxidizers and other incompatible materials.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Appropriate engineering controls: Use with adequate general or local exhaust ventilation to maintain exposures below occupational exposure limits. Use explosion-proof equipment where required.
Skin protection: Wear impervious gloves such as nitrile rubber or other impervious gloves.
Eye protection: Wear safety chemical goggles when the possibility exists for eye contact due to splashing or spraying material.
Other: Wear impervious clothing if needed to prevent any contact with this product, such as gloves, apron, boots, or whole body suit.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance (physical state, color, etc.): Clear fluid with a sweet ester odor Odor: Sweet ester odor
10. STABILITY AND REACTIVITYReactivity: Polymerization can occur.
Chemical stability: Stable when stabilized. The product is unstable at elevated temperatures and pressures.
Possibility of hazardous reactions: Methyl methacrylate can undergo hazardous polymerization if exposed to excessive heat, peroxides and polymerization catalysts.
Conditions to avoid: Avoid heat, sparks and open flames.
Incompatible materials: Avoid contact with peroxides and polymerization catalysts.
Hazardous decomposition products: Thermal decomposition may produce carbon oxides, and hydrocarbons.
11. TOXICOLOGICAL INFORMATION
Inhalation: May cause respiratory tract irritation with coughing, mucous production and shortness of breath.
Methyl methacrylate has been shown to cause irritation of the upper respiratory tract in studies with laboratory animals.
Ingestion: Swallowing may cause gastrointestinal irritation, nausea and diarrhea.
Skin contact: Causes skin irritation. Methyl methacrylate has been shown to cause severe irritation when tested undiluted on rabbit skin. Causes skin sensitization. Cases of contact dermatitis has been reported in workers exposed to methyl methacrylate.
Eye contact: May cause eye irritation. Methyl methacrylate has been shown to cause mild irritation to the conjunctiva in animal studies.
Chronic effects from short- and long-term exposure: In subchronic inhalation studies with methyl methacrylate, systemic toxic effects were seen in rats to the liver, kidney, brain, spleen and bone marrow 1000 ppm. Oral administration of methyl methacrylate to rats resulted in a NOAEL of 200 mg/kg.
Reproductive Toxicity: This product is not expected to cause adverse reproductive or developmental effects.
Methyl methacrylate did not cause reproductive effects on male fertility when animals were exposed to 9000
ppm. No teratogenicity, embryotoxicity or fetotoxicity has been observed at exposure levels up to and including 2028 ppm Sensitization: Methyl methacrylate has been shown to cause sensitization in a mouse local lymphnode assay Mutagenicity: Methyl methacrylate was negative in sister chromatid exchange assay in mammalian cells and in a vivo chromosome aberration assay.
Carcinogenicity: None of the components are listed as a carcinogen by IARC, NTP, ACGIH or OSHA.
Acute Toxicity Values:
Methyl Methacrylate: Oral rat LD50 7800 mg/kg; Inhalation rat LC50 3750 mg/L/8 hr; Dermal rabbit LD60 5000 mg/kg
12. ECOLOGICAL INFORMATION
Methyl Methacrylate: 96 hr LC50 Pimephales promelas 130 mg/L; 24 hr LC50 daphnia magna 1760 mg/L Persistence and degradability: Methyl methacrylate is readily biodegradable.
Bioaccumulative potential: Methyl methacrylate has a BCF of 2.97.
Mobility in soil: Methyl methacrylate has a high mobility in soil.
Other adverse effects: None known.
13. DISPOSAL CONSIDERATIONSDispose in accordance with all local, state and federal regulations.
14. TRANSPORT INFORMATION
Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable – product is transported only in packaged form.
Special precautions: None known
15. REGULATORY INFORMATIONCERCLA: This product has a Reportable Quantity (RQ) of 1000 lbs. (based on the RQ for Methyl Methacrylate of 1000 lbs). Releases above the RQ must be reported to the National Response Center. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations.
SARA Hazard Category (311/312): Acute Health, Chronic Health, Fire Hazard, Reactive Hazard SARA 313 Information: This product contains the following chemicals subject to Annual Release
Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372):
California Proposition 65 This product contains the following chemicals known to the State of California to cause cancer or reproductive toxicity (birth defects): None EPA TSCA Inventory: All of the ingredients in this product are listed on the EPA TSCA Inventory.
Canadian WHMIS Classification: Class B-2 (Flammable Liquid) Class D Division 2 Subdivision B (Toxic Material Causing other Toxic Effects) This product has been classified under the CPR and this MSDS discloses information elements required by the CPR.
16. OTHER INFORMATION
SDS Revision History: Converted to GHS format. All sections revised.
Date of preparation: July 13, 2014 Date of last revision: New SDS The above information is accurate to the best of our knowledge. However, since data, safety standards, and government regulations are subject to change and the conditions of handling and use, or misuse, are beyond our control, Dur-A-Flex, Inc. MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT